Burnside can you post photos of the offending valves when you get a chance.
I find it interesting that there would be a build up on the intake valves.... (Any build up should be on the exhaust valves as they are the valves the exhaust passes through. It's just air and fuel coming it the intake valves....)
Perhaps the valves are breaking down from... heat, friction, some type of chemical reaction form the fuel. burnt fuel....
Please correct me if I'm wrong. Isn't a valve made so it can spin (turn around slowly)? I think they are designed so they don't stay in the same spot all the time. If so they should wear pretty equally around the face. Wouldn't that keep any carbon off?